Regiospecific Introduction Of 4 Substituents To Porphyrin Systems At Antipodal Pyrrolenic Positions
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| Title | Regiospecific Introduction Of 4 Substituents To Porphyrin Systems At Antipodal Pyrrolenic Positions |
| Publication Type | Journal Article |
| Year of Publication | 1991 |
| Authors | Crossley, M. J., Burn P. L., Chew S. S., Cuttance F. B., and Newsom I. A. |
| Journal | Journal Of The Chemical Society-Chemical Communications |
| Volume | - |
| Issue | 21 |
| Pagination | 1564–1566 |
| Date Published | nov |
| Abstract | Electrophilic bromination occurs regiospecifically at the antipodal pyrrolenic ring of free-base porphyrins bearing substituents that fix the aromatic delocalization pathway; this new feature of porphyrin chemistry is not observed in the reactions of the corresponding metalloporphyrins as the pre-requisite bond fixation is only possible in free-base compounds. |